Organometallic chemistry in the melt phase

被引：37

作者：

Bala, Muhammad D. ^{[1
]}

Coville, Neil J. ^{[1
]}

机构：

[1] Univ Witwatersrand, Sch Chem, Inst Mol Sci, ZA-2050 Johannesburg, South Africa

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 04期

基金：

新加坡国家研究基金会;

关键词：

melt chemistry; solventless organometallic chemistry; solvent-free organometallic syntheses; green chemistry;

D O I：

10.1016/j.jorganchem.2006.10.046

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this review organometallic chemistry reactions in the melt phase are described. As will be indicated this is a viable approach to make new and known complexes. Examples from the literature highlighting procedures used to generate melts and results that have been obtained in this area of synthesis are described. Clearly there will be limitations to the use of the melt phase, and these limitations are also discussed. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：709 / 730

页数：22

共 164 条

[1] Solid-state isomerisation reactions of (η5-C5H4R)M(CO)2(PR3′)I (M = W, Mo; R = tBu, Me; R′ = Ph, OiPr3)
Adeyemi, AG
Eke, UB
Cheng, L
Cook, LM
Billing, DG
Mamba, BB
Levendis, DC
Coville, NJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (13) : 2207 - 2215
[2] Adeyemi AG, 2002, CR CHIM, V5, P387
[3] Solvent-free organometallic migratory insertion reactions
Adeyemi, OG
Coville, NJ
[J]. ORGANOMETALLICS, 2003, 22 (11) : 2284 - 2290
[4] Self-assembled organoplatinum(II) supermolecules as crystalline, SO2 gas-triggered switches
Albrecht, M
Lutz, M
Schreurs, AMM
Lutz, ETH
Spek, AL
van Koten, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21): : 3797 - 3804
[5] Natural gradient tracer test to evaluate natural attenuation of MTBE under anaerobic conditions
Amerson, I
Johnson, RL
[J]. GROUND WATER MONITORING AND REMEDIATION, 2003, 23 (01) : 54 - 61
[6] Anastas PT., 1998, Principles of green chemistry
[7] Organometallic chemistry in a conventional microwave oven: the facile synthesis of group 6 carbonyl complexes
Ardon, M
Hogarth, G
Oscroft, DTW
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (15) : 2429 - 2435
[8] Air-water transfer of MTBE, its degradation products, and alternative fuel oxygenates: The role of temperature
Arp, HPH
Schmidt, TC
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (20) : 5405 - 5412
[9] APPLICATION OF MICROWAVE DIELECTRIC LOSS HEATING EFFECTS FOR THE RAPID AND CONVENIENT SYNTHESIS OF ORGANOMETALLIC COMPOUNDS
BAGHURST, DR
MINGOS, DMP
WATSON, MJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 368 (03) : C43 - C45
[10] APPLICATION OF MICROWAVE DIELECTRIC LOSS HEATING EFFECTS FOR THE RAPID AND CONVENIENT SYNTHESIS OF COORDINATION-COMPOUNDS
BAGHURST, DR
COOPER, SR
GREENE, DL
MINGOS, DMP
REYNOLDS, SM
[J]. POLYHEDRON, 1990, 9 (06) : 893 - 895

← 1 2 3 4 5 6 7 8 9 10 →