Resolution of enantiomers in solution and determination of the chirality of extended metal atom chains

被引：27

作者：

Armstrong, Daniel W. ^{[1
]}

Cotton, F. Albert

Petrovic, Ana G.

Polavarapu, Prasad L.

Warnke, Molly M.

机构：

[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

[2] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[3] Texas A&M Univ, Mol Struct & Bonding Lab, College Stn, TX 77842 USA

[4] Vanderbilt Univ, Dept Chem, Nashville, TN 37235 USA

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 05期

关键词：

D O I：

10.1021/ic062263l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The resolution of enantiomers of extended metal atom chains of the type Ni-3[(C5H5N)(2)N](4)Cl-2 has been accomplished by chromatographic methods in solution, and the chirality was determined using vibrational circular dichroism, electronic circular dichroism, optical rotatory dispersion, and density functional theory calculations.

引用

页码：1535 / 1537

页数：3

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