The importance of Asia as a source of black carbon to the European Arctic during springtime 2013

被引：48

作者：

Liu, D. ^{[1
]}

Quennehen, B. ^{[2
,3
,4
]}

Darbyshire, E. ^{[1
]}

Allan, J. D. ^{[1
,5
]}

Williams, P. I. ^{[1
,5
]}

Taylor, J. W. ^{[1
]}

Bauguitte, S. J. -B. ^{[6
]}

Flynn, M. J. ^{[1
]}

Lowe, D. ^{[1
]}

Gallagher, M. W. ^{[1
]}

Bower, K. N. ^{[1
]}

Choularton, T. W. ^{[1
]}

Coe, H. ^{[1
]}

机构：

[1] Univ Manchester, Sch Earth Atmospher & Environm Sci, Manchester, Lancs, England

[2] Univ Paris 06, Sorbonne Univ, Paris, France

[3] Univ Versailles St Quentin, Paris, France

[4] LATMOS IPSL, CNRS INSU, Paris, France

[5] Univ Manchester, Natl Ctr Atmospher Sci, Manchester, Lancs, England

[6] Cranfield Univ, FAAM, Cranfield MK43 0AL, Beds, England

来源：

ATMOSPHERIC CHEMISTRY AND PHYSICS | 2015年 / 15卷 / 20期

基金：

英国自然环境研究理事会;

关键词：

LONG-TERM TRENDS; NORTH-AMERICA; MIXING STATE; POLLUTION TRANSPORT; OPTICAL-PROPERTIES; AIR-POLLUTION; AEROSOL; CLIMATE; EMISSIONS; MODEL;

D O I：

10.5194/acp-15-11537-2015

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Black carbon aerosol (BC) deposited to the Arctic sea ice or present in the free troposphere can significantly affect the Earth's radiation budget at high latitudes yet the BC burden in these regions and the regional source contributions are poorly constrained. Aircraft measurements of aerosol composition in the European Arctic were conducted during the Aerosol-Cloud Coupling And Climate Interactions in the Arctic (ACCACIA) campaign in March 2013. Pollutant plumes were encountered throughout the lower to upper Arctic troposphere featuring enhancements in CO and aerosol mass loadings, which were chemically speciated into BC and non-refractory sulphate and organic matter. FLEXPART-WRF simulations have been performed to evaluate the likely contribution to the pollutants from regional ground sources. By combining up-to-date anthropogenic and open fire biomass burning (OBB) inventories, we have been able to compare the contributions made to the observed pollution layers from the sources of eastern/northern Asia (AS), Europe (EU) and North America (NA). Over 90% of the contribution to the BC was shown to arise from non-OBB anthropogenic sources. AS sources were found to be the major contributor to the BC burden, increasing background BC loadings by a factor of 3-5 to 100.8 +/- 48.4 ng sm(-3) (in standard air m(3) at 273.15K and 1013.25 mbar) and 55.8 +/- 22.4 ng sm(-3) in the middle and upper troposphere respectively. AS plumes close to the tropopause (about 7.5-8 km) were also observed, with BC concentrations ranging from 55 to 73 ng sm(-3), which will potentially have a significant radiative impact. EU sources influenced the middle troposphere with a BC mean concentration of 70.8 +/- 39.1 ng sm(-3) but made a minor contribution to the upper troposphere due to the relatively high latitude of the source region. The contribution of NA was shown to be much lower at all altitudes with BC mean concentration of 20 ng sm(-3). The BC transported to the Arctic is mixed with a non-BC volume fraction representing between 90-95% of the mass, and has a relatively uniform core size distribution with mass median diameter 190-210 nm and geometric standard deviation sigma(g) = 1.55-1.65 and this varied little across all source regions. It is estimated that 60-95% of BC is scavenged between emission and receptor based on BC = 1 CO comparisons between source inventories and measurement. We show that during the springtime of 2013, the anthropogenic pollution particularly from sources in Asia, contributed significantly to BC across the European Arctic free troposphere. In contrast to previous studies, the contribution from open wildfires was minimal. Given that Asian pollution is likely to continue to rise over the coming years, it is likely that the radiative forcing in the Arctic will also continue to increase.

引用

页码：11537 / 11555

页数：19

共 74 条

[1] On the diurnal variability of particle properties related to light absorbing carbon in Mexico City [J].

Baumgardner, D. ;

Kok, G. L. ;

Raga, G. B. .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2007, 7 (10) :2517-2526

[2] Soot reference materials for instrument calibration and intercomparisons: a workshop summary with recommendations [J].

Baumgardner, D. ;

Popovicheva, O. ;

Allan, J. ;

Bernardoni, V. ;

Cao, J. ;

Cavalli, F. ;

Cozic, J. ;

Diapouli, E. ;

Eleftheriadis, K. ;

Genberg, P. J. ;

Gonzalez, C. ;

Gysel, M. ;

John, A. ;

Kirchstetter, T. W. ;

Kuhlbusch, T. A. J. ;

Laborde, M. ;

Lack, D. ;

Mueller, T. ;

Niessner, R. ;

Petzold, A. ;

Piazzalunga, A. ;

Putaud, J. P. ;

Schwarz, J. ;

Sheridan, P. ;

Subramanian, R. ;

Swietlicki, E. ;

Valli, G. ;

Vecchi, R. ;

Viana, M. .

ATMOSPHERIC MEASUREMENT TECHNIQUES, 2012, 5 (08) :1869-1887

[3] Scavenging of black carbon by ice crystals over the northern Pacific [J].

Baumgardner, D. ;

Subramanian, R. ;

Twohy, C. ;

Stith, J. ;

Kok, G. .

GEOPHYSICAL RESEARCH LETTERS, 2008, 35 (22)

[4] Bounding the role of black carbon in the climate system: A scientific assessment [J].

Bond, T. C. ;

Doherty, S. J. ;

Fahey, D. W. ;

Forster, P. M. ;

Berntsen, T. ;

DeAngelo, B. J. ;

Flanner, M. G. ;

Ghan, S. ;

Kaercher, B. ;

Koch, D. ;

Kinne, S. ;

Kondo, Y. ;

Quinn, P. K. ;

Sarofim, M. C. ;

Schultz, M. G. ;

Schulz, M. ;

Venkataraman, C. ;

Zhang, H. ;

Zhang, S. ;

Bellouin, N. ;

Guttikunda, S. K. ;

Hopke, P. K. ;

Jacobson, M. Z. ;

Kaiser, J. W. ;

Klimont, Z. ;

Lohmann, U. ;

Schwarz, J. P. ;

Shindell, D. ;

Storelvmo, T. ;

Warren, S. G. ;

Zender, C. S. .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2013, 118 (11) :5380-5552

[5] Pollution transport efficiency toward the Arctic: Sensitivity to aerosol scavenging and source regions [J].

Bourgeois, Quentin ;

Bey, Isabelle .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2011, 116

[6] The Lagrangian particle dispersion model FLEXPART-WRF version 3.1 [J].

Brioude, J. ;

Arnold, D. ;

Stohl, A. ;

Cassiani, M. ;

Morton, D. ;

Seibert, P. ;

Angevine, W. ;

Evan, S. ;

Dingwell, A. ;

Fast, J. D. ;

Easter, R. C. ;

Pisso, I. ;

Burkhart, J. ;

Wotawa, G. .

GEOSCIENTIFIC MODEL DEVELOPMENT, 2013, 6 (06) :1889-1904

[7] Characteristics, sources, and transport of aerosols measured in spring 2008 during the aerosol, radiation, and cloud processes affecting Arctic Climate (ARCPAC) Project [J].

Brock, C. A. ;

Cozic, J. ;

Bahreini, R. ;

Froyd, K. D. ;

Middlebrook, A. M. ;

McComiskey, A. ;

Brioude, J. ;

Cooper, O. R. ;

Stohl, A. ;

Aikin, K. C. ;

de Gouw, J. A. ;

Fahey, D. W. ;

Ferrare, R. A. ;

Gao, R-S. ;

Gore, W. ;

Holloway, J. S. ;

Huebler, G. ;

Jefferson, A. ;

Lack, D. A. ;

Lance, S. ;

Moore, R. H. ;

Murphy, D. M. ;

Nenes, A. ;

Novelli, P. C. ;

Nowak, J. B. ;

Ogren, J. A. ;

Peischl, J. ;

Pierce, R. B. ;

Pilewskie, P. ;

Quinn, P. K. ;

Ryerson, T. B. ;

Schmidt, K. S. ;

Schwarz, J. P. ;

Sodemann, H. ;

Spackman, J. R. ;

Stark, H. ;

Thomson, D. S. ;

Thornberry, T. ;

Veres, P. ;

Watts, L. A. ;

Warneke, C. ;

Wollny, A. G. .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2011, 11 (06) :2423-2453

[8] The scavenging processes controlling the seasonal cycle in Arctic sulphate and black carbon aerosol [J].

Browse, J. ;

Carslaw, K. S. ;

Arnold, S. R. ;

Pringle, K. ;

Boucher, O. .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2012, 12 (15) :6775-6798

[9]

Draxler RR, 1998, AUST METEOROL MAG, V47, P295

[10] A new time-of-flight aerosol mass spectrometer (TOF-AMS) - Instrument description and first field deployment [J].

Drewnick, F ;

Hings, SS ;

DeCarlo, P ;

Jayne, JT ;

Gonin, M ;

Fuhrer, K ;

Weimer, S ;

Jimenez, JL ;

Demerjian, KL ;

Borrmann, S ;

Worsnop, DR .

AEROSOL SCIENCE AND TECHNOLOGY, 2005, 39 (07) :637-658

← 1 2 3 4 5 6 7 8 →