Silica monolayer solid acid catalyst prepared by CVD

被引:39
作者
Katada, N
Niwa, M
机构
[1] Department of Materials Science, Faculty of Engineering, Tottori University, Tottori 680, Koyama-cho
关键词
silica monolayer; solid-acid catalyst; Bronsted acidity; thermal stability; mechanism of chemical vapor deposition;
D O I
10.1002/cvde.19960020402
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
For the design of novel acid catalysts it is Important to understand the principles of the generation of acidity. However, the origin of this acidity is unclear because the mixed solid-acid usually possesses a complicated structure leading to different types of sites. The CVD of silica is being used on high surface area basic oxides to provide model compounds to elucidate the formation and functioning of acid catalysts. This paper reviews these studies and also shows how novel heat resistant catalysts can be obtained.
引用
收藏
页码:125 / &
页数:11
相关论文
共 48 条
[1]   MULLITE FOR STRUCTURAL, ELECTRONIC, AND OPTICAL APPLICATIONS [J].
AKSAY, IA ;
DABBS, DM ;
SARIKAYA, M .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (10) :2343-2358
[2]  
Amato I., 1975, SINTERING CATALYSIS, P187
[3]   RECENT PROGRESS IN HIGH-TEMPERATURE CATALYTIC COMBUSTION [J].
Arai, H. ;
Machida, M. .
CATALYSIS TODAY, 1991, 10 (01) :81-94
[4]   SORPTION BEHAVIOR OF SILANATED H-MORDENITE [J].
BARRER, RM ;
VANSANT, EF ;
PEETERS, G .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 :1871-1878
[5]   STABILIZATION OF ALUMINA TOWARD THERMAL SINTERING BY SILICON ADDITION [J].
BEGUIN, B ;
GARBOWSKI, E ;
PRIMET, M .
JOURNAL OF CATALYSIS, 1991, 127 (02) :595-604
[6]   QUANTUM CHEMICAL STUDY OF ACID-BASE PROPERTIES OF METAL-OXIDES .1. [J].
GRABOWSKI, W ;
MISONO, M ;
YONEDA, Y .
JOURNAL OF CATALYSIS, 1980, 61 (01) :103-108
[7]   FACTORS FOR MAINTENANCE OF A HIGH-SURFACE-AREA OF SILICA-COATED ALPHA-ALUMINA AFTER HEATING GREATER-THAN 1573-K [J].
HORIUCHI, T ;
SUGIYAMA, T ;
MORI, T .
JOURNAL OF MATERIALS CHEMISTRY, 1993, 3 (08) :861-865
[8]  
IMIZU Y, 1994, STUD SURF SCI CATAL, V90, P339
[9]  
IMIZU Y, 1988, SHOKUBAI, V30, P388
[10]   Synthesis of thermally stable, porous silica-modified alumina via formation of a precursor in an organic solvent [J].
Inoue, M ;
Otsu, H ;
Kominami, H ;
Inui, T .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (01) :295-306