Unusual reaction of β-hydroxy α-diazo carbonyl compounds with TsNHN=CHCOCl/Et3N

被引：13

作者：

Shi, WF ^{[1
]}

Zhang, B ^{[1
]}

Liu, B ^{[1
]}

Xu, F ^{[1
]}

Xiao, FP ^{[1
]}

Zhang, H ^{[1
]}

Zhang, SW ^{[1
]}

Wang, JB ^{[1
]}

机构：

[1] Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 23期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/j.tetlet.2004.04.037

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of beta-hydroxy alpha-diazo carbonyl compounds with TsNHN=CHCOCl/Et3N gave beta-(p-tolylsulfonyl) alpha,beta-unsaturated carbonyl compounds or beta-(p-tolylsulfonyl) alpha-diazo esters. The reaction mechanism is discussed. (C) 2004 Elsevier Ltd. All rights reserved.

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页码：4563 / 4566

页数：4

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