Microwave-assisted synthesis of phthalocyanine-porphyrin complex and its photoelectric conversion properties

被引：41

作者：

Liu, MO ^{[1
]}

Hu, AT ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 30043, Taiwan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 15期

关键词：

phthalocyanine; porphyrin; microwave; double-decker; photoelectric conversion;

D O I：

10.1016/j.jorganchem.2004.05.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A soluble phthalocyanine-porphyrin complex (Lu(TBPor)Pc) has been rapidly synthesized from a lutetium porphyrin (Lu(TBPor)OAc) and a metal-free phthalocyanine (H-2(TBPc)) under microwave irradiation. Its photoelectric conversion properties have also been investigated. The experimental results reveal that Lu(TBPor)Pc exhibits better photoelectric conversion effect than Lu(TBPor)OAc, H-2(TBPc), and Lu(TBPor)OAc/H-2(TBPc) blend. Furthermore, we have also introduced a n-type photoconductor (N,N'-bis(1,5-dimethylhexyl)-3,4:9,10-perylenebis(dicarboximide)(PDHEP)) and TiO2 into Lu(TBPor)Pc photoelectric cell to fabricate a SnO2/Lu(TBPor)Pc + PDHEP + TiO2/Al photoelectric cell, exhibiting the largest short-circuit photocurrent (691.3 muA/cm(2)) among all of lab-made cells under illumination of white light (1.2 mW/cm(2)). (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：2450 / 2455

页数：6

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