Metastable high-pressure phases of low-Z compounds:: creation of a new chemistry or a prompt for old principles?

被引：26

作者：

Brazhkin, VV ^{[1
]}

Lyapin, AG ^{[1
]}

机构：

[1] Russian Acad Sci, Inst High Pressure Phys, Troitsk 142190, Moscow Region, Russia

来源：

NATURE MATERIALS | 2004年 / 3卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1038/nmat1186

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recent experiments demonstrate that high pressure is a powerful tool for the synthesis of new unusual inorganic polymers consisting of low-Z elements. However, experience within organic chemistry, for example, polyethylene, provides evidence that polymeric phases with high thermal stability can be potentially synthesised by conventional chemical techniques without applying high pressure.

引用

页码：497 / 500

页数：4

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