Nanoscale spherical architectures fabricated by metal coordination of multiple dipyrrin moieties

被引:158
作者
Maeda, Hiromitsu [1 ]
Hasegawa, Masahiro
Hashimoto, Takashi
Kakimoto, Takuya
Nishio, Satoru
Nakanishi, Takashi
机构
[1] Ritsumeikan Univ, Dept Biosci & Biotechnol, Kusatsu 5258577, Japan
[2] Ritsumeikan Univ, Dept Appl Chem, Fac Sci & Engn, Kusatsu 5258577, Japan
[3] Inst Mol Sci, Dept Appl Mol Sci, Okazaki, Aichi 4448787, Japan
[4] Natl Inst Mat Sci, Supermol Grp, Organ Nanomat Ctr, Tsukuba, Ibaraki 3050044, Japan
[5] Natl Inst Mat Sci, ICYS, Tsukuba, Ibaraki 3050044, Japan
关键词
D O I
10.1021/ja0637301
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Phenylethynyl-bridged dipyrrin "dimers" have performed ZnII complexation to give coordination polymers, which provided the fluorescent colloidal spherical objects in solution as well as on the substrate according to the spacer units. Using a mixture of THF and water, unique morphologies, such as bell-shaped and "golf ball"-like architectures, were observed. Copyright © 2006 American Chemical Society.
引用
收藏
页码:10024 / 10025
页数:2
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