A study of the gas-phase behaviour of [Os6(CO)18] and its high yield synthesis using UV laser desorption/ionisation mass spectrometry

被引：10

作者：

Dollard, WJ

Dyson, PJ ^{[1
]}

Jackson, T

Johnson, BFG

McIndoe, JS

Langridge-Smith, PRR

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] ICI Uniqema, New Castle, DE 19720 USA

[3] ICI Technol, Res & Technol Ctr, Middlesbrough TS90 8JE, Cleveland, England

[4] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[5] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 12期

关键词：

mass spectrometry; osmium complexes; carbonyl complexes; cluster complexes; laser desorption/ionisation;

D O I：

10.1016/S1387-7003(99)00159-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ultraviolet laser desorption/ionisation time-of-flight mass spectra of [Os-6(CO)(18)] recorded in both the positive and negative mode exhibit features that correlate with the macroscopic physiochemical properties of the cluster. In addition, hexanuclear clusters, related to [Os-6(CO)(18)], are the major products of the laser desorption/ionisation of [Os-3(CO)(10)(NCMe)(2)] and [H2Os3(CO)(10)], paralleling macroscopic synthetic protocols. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：587 / 590

页数：4

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