Cross-Stacked Carbon Nanotube Sheets Uniformly Loaded with SnO2 Nanoparticles: A Novel Binder-Free and High-Capacity Anode Material for Lithium-Ion Batteries

被引:428
作者
Zhang, Hao-Xu [1 ,2 ]
Feng, Chen [1 ,2 ]
Zhai, Yong-Chao [1 ,2 ]
Jiang, Kai-Li [1 ,2 ]
Li, Qun-Qing [1 ,2 ]
Fan, Shou-Shan [1 ,2 ]
机构
[1] Tsinghua Univ, Dept Phys, Beijing 100084, Peoples R China
[2] Tsinghua Univ, Tsinghua Foxconn Nanotechnol Res Ctr, Beijing 100084, Peoples R China
关键词
METAL NANOPARTICLES; MESOPOROUS SNO2; AMORPHOUS OXIDE; COMPOSITE; TIN; STORAGE; ELECTRODES; GROWTH; MICROSPHERES; DEPOSITION;
D O I
10.1002/adma.200802290
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
SnO2-carbon nanotube (CNT) composite sheets are synthesized using poly(vinyl-pyrrolidone) to uniformly load a monolayer of SnO2 nanoparticles onto the surfaces of CNTs and CNT bundles within cross-stacked CNT sheets. When they are used as high-capacity (over 850 mA h g(-1)) and binder-free anodes in rechargeable lithium-ion batteries, they exhibit good cycle performance, as shown in the lower portion of the figure.
引用
收藏
页码:2299 / +
页数:7
相关论文
共 51 条
  • [1] Decoration of activated carbon nanotubes with copper and nickel
    Ang, LM
    Hor, TSA
    Xu, GQ
    Tung, CH
    Zhao, SP
    Wang, JLS
    [J]. CARBON, 2000, 38 (03) : 363 - 372
  • [2] Electroless plating of metals onto carbon nanotubes activated by a single-step activation method
    Ang, LM
    Hor, TSA
    Xu, GQ
    Tung, CH
    Zhao, SP
    Wang, JLS
    [J]. CHEMISTRY OF MATERIALS, 1999, 11 (08) : 2115 - 2118
  • [3] Thin-film crystalline SnO2-lithium electrodes
    Brousse, T
    Retoux, R
    Herterich, U
    Schleich, DM
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (01) : 1 - 4
  • [4] High capacity Li ion battery anodes using Ge nanowires
    Chan, Candace K.
    Zhang, Xiao Feng
    Cui, Yi
    [J]. NANO LETTERS, 2008, 8 (01) : 307 - 309
  • [5] High-performance lithium battery anodes using silicon nanowires
    Chan, Candace K.
    Peng, Hailin
    Liu, Gao
    McIlwrath, Kevin
    Zhang, Xiao Feng
    Huggins, Robert A.
    Cui, Yi
    [J]. NATURE NANOTECHNOLOGY, 2008, 3 (01) : 31 - 35
  • [6] On the aggregation of tin in SnO composite glasses caused by the reversible reaction with lithium
    Courtney, IA
    McKinnon, WR
    Dahn, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (01) : 59 - 68
  • [7] Electrochemical and in situ x-ray diffraction studies of the reaction of lithium with tin oxide composites
    Courtney, IA
    Dahn, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (06) : 2045 - 2052
  • [8] Key factors controlling the reversibility of the reaction of lithium with SnO2 and Sn2BPO6 glass
    Courtney, IA
    Dahn, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (09) : 2943 - 2948
  • [9] In-situ 119Sn Mossbauer effect studies of the reaction of lithium with SnO and SnO:0.25 B2O3:0.25 P2O5 glass
    Courtney, IA
    Dunlap, RA
    Dahn, JR
    [J]. ELECTROCHIMICA ACTA, 1999, 45 (1-2) : 51 - 58
  • [10] Facile one-pot synthesis of mesoporous SnO2 microspheres via nanoparticles assembly and lithium storage properties
    Demir-Cakan, Rezan
    Hu, Yong-Sheng
    Antonietti, Markus
    Maier, Joachim
    Titirici, Maria-Magdalena
    [J]. CHEMISTRY OF MATERIALS, 2008, 20 (04) : 1227 - 1229