Polarization switching of crystal structure in the nonphotochemical light-induced nucleation of supersaturated aqueous glycine solutions

被引:259
作者
Garetz, BA
Matic, J
Myerson, AS
机构
[1] Polytech Univ, Dept Chem Engn & Chem, Brooklyn, NY 11201 USA
[2] IIT, Dept Chem Engn, Chicago, IL 60616 USA
基金
美国国家科学基金会;
关键词
D O I
10.1103/PhysRevLett.89.175501
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
By switching between linear and circular polarization in the irradiation of supersaturated solutions of the amino acid glycine in water with intense nanosecond pulses of near-infrared laser light, we have obtained the gamma and alpha phases, respectively, through nonphotochemical light-induced nucleation (NPLIN). This is the first report of light polarization controlling crystal structure. The intensity dependence of NPLIN in aqueous urea is also reported.
引用
收藏
页码:1 / 175501
页数:4
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