Preparation and spectroelectrochemical properties of poly(N-phenylphenazasiline)

被引：9

作者：

Hayashi, H

Nakao, H

Imase, T

机构：

[1] Nagoya Municipal Ind Res Inst, Atsuta Ku, Nagoya, Aichi 4560058, Japan

[2] Natl Agr Res Ctr, Tsukuba, Ibaraki 3058666, Japan

[3] Yamagata Univ, Venture Business Lab, Yonezawa, Yamagata 9928510, Japan

来源：

POLYMER JOURNAL | 2002年 / 34卷 / 05期

关键词：

poly(phenazasiline); spectroelectrochemistry; molecular orbital calculations; effect of the substituent;

D O I：

10.1295/polymj.34.400

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Preparation of phenazasiline-containing π-conjugated polymers by electrochemical oxidation was presented. The effect of Si unit of monosilanylene and disilanylene bridged diphenylamines by spectroelectrochemical measurement was also reported. Infrared (IR) spectra, nuclear magnetic resonance (NMR) spectra and ultraviolet (UV) spectra were measured using three different spectrometers. The resulting polymers exhibited electrochromism and high efficiency as hole transporting polymeric material.

引用

收藏

页码：400 / 404

页数：5

相关论文

共 15 条

[1] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[2]

Frisch M.J., 2016, Gaussian 16 Revision C. 01. 2016, V16, P01

[3] Preparation and properties of π-conjugated polymer with phenazasiline units [J].

Hayashi, H ;

Nakao, H ;

Adachi, A ;

Kimura, H ;

Okita, K ;

Hayashi, T ;

Tanaka, M .

CHEMISTRY LETTERS, 2000, (06) :688-689

[4]

HAYASHI H, 1999, 76 ANN M CHEM SOC JA

[5] Preparation of new polymers containing an azobenzene group in the side chain by palladium-catalyzed polymer reaction and polycondensation and characterization of the polymers [J].

Kanbara, T ;

Oshima, M ;

Imayasu, T ;

Hasegawa, K .

MACROMOLECULES, 1998, 31 (25) :8725-8730

[6] Preparation of poly(diphenylamine-4,4′-diyl) and related random copolymers by organometallic polycondensation.: Electrical, electrochemical, and optical properties [J].

Kim, SB ;

Harada, K ;

Yamamoto, T .

MACROMOLECULES, 1998, 31 (04) :988-993

[7] PHENAZASILINE-CONTAINING POLYAMIDES AND POLYESTERS [J].

KONDO, H ;

SATO, M ;

YOKOYAMA, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1983, 21 (01) :165-173

[8] DEVELOPMENT OF THE COLLE-SALVETTI CORRELATION-ENERGY FORMULA INTO A FUNCTIONAL OF THE ELECTRON-DENSITY [J].

LEE, CT ;

YANG, WT ;

PARR, RG .

PHYSICAL REVIEW B, 1988, 37 (02) :785-789

[9] AN ELECTROCHROMIC WINDOW BASED ON POLY(N-METHYL-10,10-DIMETHYLPHENAZASILINE) AND ITO ELECTRODES [J].

MASTRAGOSTINO, M ;

ZANELLI, A ;

CASALBOREMICELI, G ;

GERI, A .

SYNTHETIC METALS, 1995, 68 (02) :157-160

[10] Spectroelectrochemical properties of polyphenazasiline [J].

Nakao, H ;

Hayashi, H ;

Okita, K .

BUNSEKI KAGAKU, 2000, 49 (03) :169-174