Transition metal disubstituted ternary heteropolyoxometallates: Synthesis, characterization, crystal structure and magnetic properties

被引：12

作者：

Niu, JY

Wang, JP

You, XZ

Mak, TCW

Zhou, ZY

机构：

[1] NANJING UNIV,CTR ADV STUDIES & TECHNOL MICRSTRUCT,STATE KEY LAB COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA

[2] CHINESE UNIV HONG KONG,DEPT CHEM,HONG KONG,NEW TERR,HONG KONG

来源：

POLYHEDRON | 1996年 / 15卷 / 22期

基金：

中国国家自然科学基金;

关键词：

transition metal; heteropolyoxometallate; Keggin structure; crystal structure disubstituted; ternary;

D O I：

10.1016/0277-5387(96)00142-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of transition metal disubstituted ternary heteropolyoxometallates, [TBA]H-4(3)[PW(3)Mo(7)M(2)O(38)(H2O)(2)]. 2H(2)O (M = Co2+, Ni2+ and Cu2+) [TBA]H-4[PW(3)Mo(7)M(2)O(38)(H2O)(2)]. 2H(2)O (M = Cr3+, Fe3+) and [TBA]H-4(2)[PW3Mo6V3O40]. 2H(2)O, have been synthesized by reaction of Na9PW3Mo6O34. 10H(2)O and the corresponding results of the transition metal in water, and recrystallized in a mixed acetone/water solvent. They were characterized by elemental analyses, IR spectra and electronic spectra. The crystal structure of [TBA]H-4(3)[PW3Mo7Cu2O38(H2O)(2)]. 2H(2)O has been determined, The magnetic susceptibility data indicate that [TBA]H-4[PW3Mo7Fe2O38 (H2O)(2)]. 2H(2)O has weak ferromagnetic properties. Copyright (C) 1996 Elsevier Science Ltd

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页码：3963 / 3969

页数：7

相关论文

共 19 条

[1] A NEW GENERAL STRUCTURAL CATEGORY OF HETEROPOLYELECTROLYTES . UNUSUAL MAGNETIC AND THERMAL CONTRACTION PHENOMENA [J].

BAKER, LCW ;

BAKER, VS ;

ERIKS, K ;

POPE, MT ;

SHIBATA, M ;

ROLLINS, OW ;

FANG, JH ;

KOH, LL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (10) :2329-&

[2] A NEW FUNDAMENTAL TYPE OF INORGANIC COMPLEX - HYBRID BETWEEN HETEROPOLY AND CONVENTIONAL COORDINATION COMPLEXES - POSSIBILITIES FOR GEOMETRICAL ISOMERISMS IN 11-HETEROPOLY, 12-HETEROPOLY, 17-HETEROPOLY, AND 18-HETEROPOLY DERIVATIVES [J].

BAKER, LCW ;

FIGGIS, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (12) :3794-&

[3] DODECATUNGSTOPHOSPHORIC ACID HEXAHYDRATE, (H5O2+)3(PW12O403-) - TRUE STRUCTURE OF KEGGINS PENTAHYDRATE FROM SINGLE-CRYSTAL X-RAY AND NEUTRON-DIFFRACTION DATA [J].

BROWN, GM ;

NOESPIRLET, MR ;

BUSING, WR ;

LEVY, HA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1977, 33 (APR15) :1038-1046

[4] 1ST FERROMAGNETIC INTERACTION IN A HETEROPOLY COMPLEX - [COII4O14(H2O)2(PW9O27)2]10- - EXPERIMENT AND THEORY FOR INTRAMOLECULAR ANISOTROPIC EXCHANGE INVOLVING THE 4 CO(II) ATOMS [J].

CASANPASTOR, N ;

BASSERRA, J ;

CORONADO, E ;

POURROY, G ;

BAKER, LCW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (26) :10380-10383

[5]

Craig L. H., 1985, J AM CHEM SOC, V107, P5148

[6] REINTERPRETATION OF 5 RECENT CRYSTAL-STRUCTURES OF HETEROPOLY AND ISOPOLY COMPLEXES - DIVANADODECAMOLYBDOPHOSPHATE, TRIVANADOENNEAMOLYBDOPHOSPHATE, GAMMA-DODECATUNGSTOPHOSPHATE, THE DODECAMOLYBDATE-DODECAMOLYBDOMOLYBDATE BLUE COMPLEX, AND DIHYDROGEN DECAVANADATE [J].

EVANS, HT ;

POPE, MT .

INORGANIC CHEMISTRY, 1984, 23 (04) :501-504

[7] TRIVACANT HETEROPOLYTUNGSTATE DERIVATIVES - THE RATIONAL SYNTHESIS, CHARACTERIZATION, AND W-183 NMR-SPECTRA OF P2W18M4(H2O)2O68(10-) (M = CO, CU, ZN) [J].

FINKE, RG ;

DROEGE, M ;

HUTCHINSON, JR ;

GANSOW, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (06) :1587-1589

[8] MAGNETIC CHARACTERIZATION OF TETRANUCLEAR COPPER(II) AND COBALT(II) EXCHANGE-COUPLED CLUSTERS ENCAPSULATED IN HETEROPOLYOXOTUNGSTATE COMPLEXES - STUDY OF THE NATURE OF THE GROUND-STATES [J].

GOMEZGARCIA, CJ ;

CORONADO, E ;

BORRASALMENAR, JJ .

INORGANIC CHEMISTRY, 1992, 31 (09) :1667-1673

[9] CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF K5.5NA1.5[PW10CU2(H2O)2O38].13H2O - SUBSTITUTED KEGGIN HETEROPOLYTUNGSTATES OF THE TYPE PW10CU2 CONTAINING EXCHANGE-COUPLED COPPER PAIRS [J].

GOMEZGARCIA, CJ ;

CORONADO, E ;

GOMEZROMERO, P ;

CASANPASTOR, N .

INORGANIC CHEMISTRY, 1993, 32 (01) :89-93

[10]

GOMEZGARCIA CJ, 1990, J APPL PHYS, V9, P5995