Electrorheoloical behavior of chitosan dicarboxylate suspensions

被引:3
作者
Choi, US [1 ]
Ko, YG [1 ]
机构
[1] Korea Inst Sci & Technol, Tribol Ctr, Seoul 130650, South Korea
来源
INTERNATIONAL JOURNAL OF MODERN PHYSICS B | 2002年 / 16卷 / 17-18期
关键词
D O I
10.1142/S0217979202012578
中图分类号
O59 [应用物理学];
学科分类号
摘要
The electrorheological (ER) behavior of chitosan dicarboxylate suspensions in silicone oil was investigated by varying the electric fields, volume fractions of particles, and shear rates, respectively. The chitosan dicarboxylate susepnsions showed a typical ER response caused by the polarizability of an amide polar group and shear yield stress due to the formation of multiple chains upon application of an electric,field. Of these, chitosan malonicate suspension represented slightly higher rheological performance than any other suspensions due to dependent upon the carbon chain length. The shear stress for the suspension exhibited a linear dependence on an electric field power of 1.88. On the basis of the results, the newly synthesized chitosan dicarboxylate suspensions were found to be an anhydrous ER fluid.
引用
收藏
页码:2501 / 2506
页数:6
相关论文
共 12 条
[1]   MATERIALS AND MECHANISMS IN ELECTRORHEOLOGY [J].
BLOCK, H ;
KELLY, JP ;
QIN, A ;
WATSON, T .
LANGMUIR, 1990, 6 (01) :6-14
[2]  
BLOCK H, 1988, J PHYS D, V21, P166
[3]  
CONRAD H, 1995, PROGRESS IN ELECTRORHEOLOGY, P55
[4]  
CONRAD H, 1992, J MODN PHYS B, V16, P2575
[5]  
Filisko F. E., 1991, P INT C EL FLUIDS CA, P16
[6]  
KAWAKAMI T, 1997, PROGR ELECTRORHEOLOG, P58
[7]   STUDIES ON THE STEADY-SHEAR BEHAVIOR OF ELECTRORHEOLOGICAL SUSPENSIONS [J].
KLINGENBERG, DJ ;
ZUKOSKI, CF .
LANGMUIR, 1990, 6 (01) :15-24
[8]   SYNTHESIS AND CHARACTERIZATION OF POLY(ALKYLANILINES) [J].
LECLERC, M ;
GUAY, J ;
DAO, LH .
MACROMOLECULES, 1989, 22 (02) :649-653
[9]  
Li Y, 1995, ASME, V235, P29
[10]   ON THE CONDUCTIVITY MODEL FOR THE ELECTRORHEOLOGICAL EFFECT [J].
TANG, X ;
WU, C ;
CONRAD, H .
JOURNAL OF RHEOLOGY, 1995, 39 (05) :1059-1073