m-Xylene transformation over NiS/Al2O3-USY hybrid catalysts - Effects of hydrogen spillover

m-Xylene transformation (isomerization and aromatics hydrogenation) on Y zeolite (USY) was markedly promoted by the physically mixed sulfided nickel supported on Al2O3 (NiS/Al2O3) in the presence of hydrogen, while NiS/Al2O3 showed no activity for these reactions, and coke deposition on USY and m-xylene disproportionation were not affected by NiS/Al2O3. Also, under nitrogen atmosphere, all reactions were unaffected by NiS/Al2O3. Studies of H-D exchange of OH groups on USY zeolite with gaseous D-2 by FT-IR spectroscopy showed that the ratio of the exchange rate of USY, Al2O3-USY and NiS/Al2O3-USY catalyst was 3.8, 1 and 14.5, respectively, at 523 K and 62.5 kPa D-2. It was concluded that the H-D exchange of OH groups (including Bronsted acid sites) on USY surface in the NiS/Al2O3-USY catalyst was mainly due to hydrogen spillover through NiS site dissociating gaseous hydrogen, with the spillover hydrogen migrating to the USY surface, This probably promoted m-xylene isomerization and helped maintain a higher activity of hydrogenation for aromatic rings on the zeolite.