Electrical characterization of Fermi level pinning in metal/3,4,9,10 perylenetetracarboxylic dianhydride interfaces

被引:18
作者
Agrawal, Ruchi [1 ]
Ghosh, Subhasis [1 ]
机构
[1] Jawaharlal Nehru Univ, Sch Phys Sci, New Delhi 110067, India
关键词
D O I
10.1063/1.2398930
中图分类号
O59 [应用物理学];
学科分类号
摘要
Systematic studies of current injection from different metal electrodes to metal/3,4,9,10 perylenetetracarboxylic dianhydride (PTCDA) interfaces have been carried out. It has been observed that the barrier for carrier injection cannot be explained by simple vacuum alignment scheme. Moreover, injection barrier is almost independent of metal work function. These observations are explained by the changes of barrier height due to interface dipole barrier which compensate for the difference of work function of PTCDA and metals, leading to metal independent injection barrier and Fermi level pinning at metal/PTCDA interfaces. (c) 2006 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 18 条
[1]   Exchangelike effects for closed-shell adsorbates:: Interface dipole and work function -: art. no. 096104 [J].
Bagus, PS ;
Staemmler, V ;
Wöll, C .
PHYSICAL REVIEW LETTERS, 2002, 89 (09) :961041-961044
[2]   Characterization of the interface dipole at organic/metal interfaces [J].
Crispin, X ;
Geskin, V ;
Crispin, A ;
Cornil, J ;
Lazzaroni, R ;
Salaneck, WR ;
Brédas, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (27) :8131-8141
[3]   Metal-dependent charge transfer and chemical interaction at interfaces between 3,4,9,10-perylenetetracarboxylic bisimidazole and gold, silver and magnesium [J].
Hill, I. G. ;
Schwartz, J. ;
Kahn, A. .
ORGANIC ELECTRONICS, 2000, 1 (01) :5-13
[4]   Molecular level alignment at organic semiconductor-metal interfaces [J].
Hill, IG ;
Rajagopal, A ;
Kahn, A ;
Hu, Y .
APPLIED PHYSICS LETTERS, 1998, 73 (05) :662-664
[5]   Energy level alignment at organic/metal interfaces studied by UV photoemission: Breakdown of traditional assumption of a common vacuum level at the interface [J].
Ishii, H ;
Seki, K .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 1997, 44 (08) :1295-1301
[6]  
Ishii H, 1999, ADV MATER, V11, P605, DOI 10.1002/(SICI)1521-4095(199906)11:8<605::AID-ADMA605>3.0.CO
[7]  
2-Q
[8]   Electronic structure and electrical properties of interfaces between metals and π-conjugated molecular films [J].
Kahn, A ;
Koch, N ;
Gao, WY .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (21) :2529-2548
[9]   Schottky energy barrier and charge injection in metal/copper-phthalocyanine/metal structures [J].
Mahapatro, AK ;
Ghosh, S .
APPLIED PHYSICS LETTERS, 2002, 80 (25) :4840-4842