Effect of calculation method on values of Hansen Solubility Parameters of polymers

被引:34
作者
Gharagheizi, Farhad [1 ]
Sattari, Mehdi [1 ]
Angaji, Mahmood Torabi [1 ]
机构
[1] Univ Tehran, Fac Engn, Dept Chem Engn, Tehran, Iran
关键词
Solubility Parameter; Hansen Solubility Parameter; Glycol Monoethyl Ether; Ethylene Glycol Monomethyl Ether; Monobutyl Ether;
D O I
10.1007/s00289-006-0568-5
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The simplest experimental method to determine the Hansen Solubility Parameters (HSP) for a polymer is to evaluate whether or not it dissolves in selected solvents. The solvents dissolve the polymer have HSP closer to it than those which don't. Then a computer program can be used to find the HSP of the selected polymer. In this work, the effect of calculation method on the values of HSP has been analyzed completely. The results show that optimization method for calculation of HSP is an important factor in the precision of obtained values of these parameters.
引用
收藏
页码:377 / 384
页数:8
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