Hydrogen-bonding-directed layer-by-layer assembly of conjugated polymers

被引:53
作者
Liang, Z
Cabarcos, OM
Allara, DL
Wang, Q [1 ]
机构
[1] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
[2] Penn State Univ, Dept Chem, University Pk, PA 16802 USA
关键词
D O I
10.1002/adma.200305793
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Poly(phenylenevinylene) polymers, functionalized with either amine or carboxyl acid groups (see Figure), have been synthesized and assembled using layer-by-layer deposition. This hydrogen-bonding-driven self-assembly produces conjugated polymer multilayer films with molecular-level controlled thickness and architecture. The approach enables the creation of robust thin films via a thermally induced cross-linking reaction.
引用
收藏
页码:823 / +
页数:6
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