Ir-catalyzed C-H activation in the synthesis of borylated ferrocenes and half sandwich compounds

被引：52

作者：

Datta, A ^{[1
]}

Köllhofer, A ^{[1
]}

Plenio, H ^{[1
]}

机构：

[1] Tech Univ Darmstadt, Inst Organ Chem, D-64287 Darmstadt, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 13期

关键词：

D O I：

10.1039/b403419h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex generated from 1/2 [Ir(OMe)(cod)](2) and 4,4'-di-tertbutyl-2,2'-bipyridine catalyzes the regioselective borylation of ferrocenes, CpMn(CO)(3) and CPMO(CO)(3)CH3 with a stoichiometric amount of B(2)pin(2).

引用

页码：1508 / 1509

页数：2

共 19 条

[1] A concise update on the applications of chiral ferrocenyl phosphines in homogeneous catalysis leading to organic synthesis
Colacot, TJ
[J]. CHEMICAL REVIEWS, 2003, 103 (08) : 3101 - 3118
[2] Chemical redox agents for organometallic chemistry
Connelly, NG
Geiger, WE
[J]. CHEMICAL REVIEWS, 1996, 96 (02) : 877 - 910
[3] Asymmetric catalysis with chiral ferrocene ligands
Dai, LX
Tu, T
You, SL
Deng, WP
Hou, XL
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (09) : 659 - 667
[4] Ishiyama T, 2002, ANGEW CHEM INT EDIT, V41, P3056, DOI 10.1002/1521-3773(20020816)41:16<3056::AID-ANIE3056>3.0.CO
[5] 2-#
[6] Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate
Ishiyama, T
Takagi, J
Ishida, K
Miyaura, N
Anastasi, NR
Hartwig, JF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (03) : 390 - 391
[7] Mechanism of homogeneous Ir(III) catalyzed regioselective arylation of olefins
Oxgaard, J
Muller, RP
Goddard, WA
Periana, RA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) : 352 - 363
[8] Polyferrocenes: metallopolymers with tunable and high refractive indices
Paquet, C
Cyr, PW
Kumacheva, E
Manners, I
[J]. CHEMICAL COMMUNICATIONS, 2004, (02) : 234 - 235
[9] PERSEGHINI M, 2002, SCI SYNTHESIS HOUBEN, V8
[10] Plenio H, 2001, CHEM-EUR J, V7, P4438, DOI 10.1002/1521-3765(20011015)7:20<4438::AID-CHEM4438>3.0.CO

← 1 2 →