Time dependent EC′, ECE and EC2E mechanisms at microdisc electrodes:: simulations using adaptive finite element methods

被引：10

作者：

Harriman, K ^{[1
]}

Gavaghan, DJ ^{[1
]}

Süli, E ^{[1
]}

机构：

[1] Univ Oxford, Comp Lab, Oxford OX1 3QD, England

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2004年 / 569卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

adaptive finite element method; microelectrode; EC ' mechanism; ECnE mechanism;

D O I：

10.1016/j.jelechem.2004.01.035

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In this paper we extend the work in [Electrochem. Commun. 5 (2003) 519] to more complex reaction mechanisms. We use the adaptive finite element algorithm described there to simulate the chronoamperometric current for EC' reaction mechanisms (catalytic reaction mechanisms) at inlaid and recessed microdisc electrodes and for ECE and EC2E reaction mechanisms at microdisc electrodes. (C) 2004 Elsevier B.V. All rights reserved.

引用

收藏

页码：35 / 46

页数：12

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