Palladium catalyzed intramolecular hydrocarbonation of allenes leading to carbocycles

被引：60

作者：

Meguro, M ^{[1
]}

Kamijo, S ^{[1
]}

Yamamoto, Y ^{[1
]}

机构：

[1] TOHOKU UNIV,GRAD SCH SCI,DEPT CHEM,SENDAI,MIYAGI 98077,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 41期

关键词：

D O I：

10.1016/0040-4039(96)01609-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intramolecular hydrocarbonation of certain allenes (1 and 3), bearing active methyne groups al the terminus of the carbon chain, proceeded smoothly in the presence of catalytic amounts of palladium complex ([(eta(3)-C3H5)PdCl](2)-dppf) to give the corresponding carbocycles (2 and 4, respectively) in good to high yields. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：7453 / 7456

页数：4

共 27 条

[1] ANDELL OS, 1983, ACTA CHEM SCAND B, V40, P184
[2] RULES FOR RING-CLOSURE
BALDWIN, JE
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (18) : 734 - 736
[3] BESSON L, 1995, TETRAHEDRON LETT, V36, P3856
[4] HEGEDUS LS, 1992, COMPREHENSIVE ORGANI, V4, P571
[5] SYNTHESIS OF NOVEL RHENIUM(I) ENOLATE COMPLEXES AS ACTIVE KEY INTERMEDIATES IN THE CATALYTIC ALDOL-TYPE REACTION
HIRANO, M
ITO, Y
HIRAI, M
FUKUOKA, A
KOMIYA, S
[J]. CHEMISTRY LETTERS, 1993, (12) : 2057 - 2060
[6] JOLLY PW, 1990, SYNTHESIS-STUTTGART, P771
[7] JUNG ME, 1992, COMPREHENSIVE ORGANI, V4, P1
[8] Knochel P., 1991, COMPREHENSIVE ORGANI, V4, P865
[9] KUNDIG KP, 1989, TETRAHEDRON, V44, P6855
[10] LEE VJ, 1992, COMPREHENSIVE ORGANI, V4, P69

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