Poly(3,4-ethylenedioxythiophene)V2O5 hybrids for lithium batteries

被引：25

作者：

Kwon, CW

Murugan, AV

Campet, G

Portier, J

Kale, BB

Vijaymohanan, K

Choy, JH

机构：

[1] Inst Chim Mat Condensee Bordeaux, F-33608 Pessac, France

[2] Govt India, Minist Informat Technol, Ctr Mat Elect Technol, Pune 411008, Maharashtra, India

[3] Natl Chem Lab, Phys & Mat Chem Div, Pune 411008, Maharashtra, India

[4] Seoul Natl Univ, Sch Chem & Mol Engn, Natl Nanohybrid Mat Lab, Seoul 151747, South Korea

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2002年 / 4卷 / 05期

关键词：

vanadium oxide; poly(3,4-ethylenedioxythiophene); lithium battery; electrode material; hybrid; bidimensionality;

D O I：

10.1016/S1388-2481(02)00316-8

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A series of hybrid electrode materials, poly(3,4-ethylenedioxythiophene)/V2O5, has been synthesized using an oxidative insertion and polymerization reaction. FTIR, X-ray diffraction and transmission electron microscopy studies have shown that the incorporation of polymer between V2O5 slabs leads to an enhanced bidimensionality. The electrochemical lithium capacity has been increased up to similar to330 mAh/g at the second discharge in the range of 2.0-4.4 V vs. Li. This improvement of electrochemical performance compared to pristine V2O5 is attributed to the higher electric conductivity and enhanced bidimensionality. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：384 / 387

页数：4

共 17 条

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