Synthesis of oligomeric anilines

被引:175
作者
Zhang, WJ [1 ]
Feng, J [1 ]
MacDiarmid, AG [1 ]
Epstein, AJ [1 ]
机构
[1] OHIO STATE UNIV,DEPT PHYS,COLUMBUS,OH 43210
关键词
polyaniline and derivatives; coupling reactions; elemental analysis; infrared spectroscopy; UV-Vis-NIR;
D O I
10.1016/S0379-6779(97)80674-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Parent aniline oligomers such as tetramer and ''16-mer'' have been synthesized by a general method. This method can be used to synthesize other oligomers by selecting appropriate ratios of reactants and appropriate oxidants. The oligomers were characterized by UV/Vis, IR, NMR, mass spectroscopy, GPC and elemental analysis. The conductivities of HCl doped oligomers were lower than that of polyaniline.
引用
收藏
页码:119 / 120
页数:2
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