Reactivity of a rhodium(I) complex towards oxygen enhanced by a cyano ligand.: Structure of [Rh(CN)(O2)(PPh3)2(XNC)] (XNC = xylyl isocyanide)

被引：11

作者：

Cîrcu, V ^{[1
]}

Fernandes, MA ^{[1
]}

Carlton, L ^{[1
]}

机构：

[1] Univ Witwatersrand, Sch Chem, Inst Mol Sci, Johannesburg, South Africa

来源：

POLYHEDRON | 2002年 / 21卷 / 18期

关键词：

rhodium; cyano; dioxygen; enhanced reactivity; structures;

D O I：

10.1016/S0277-5387(02)01056-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Rh(CN)(O-2)(PPh3)(2)(XNC)](CH2Cl2) has been obtained under ambient conditions from solutions containing trans [Rh(CN)(PPh3)2(XNC)] upon exposure to air. The compound is unusual in that analogues containing, the more strongly electron-donating ligands Cl-, N-3(-) and NCO- (among others) in place of CN- are not formed. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1775 / 1778

页数：4

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