A highly selective and sensitive inorganic/organic hybrid polymer fluorescence "turn-on" chemosensory system for iron cations

被引：193

作者：

Fan, Li-Juan ^{[1
]}

Jones, Wayne E., Jr. ^{[1
]}

机构：

[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 21期

关键词：

D O I：

10.1021/ja0612697

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polymer-based fluorescence turn-on" chemosensor is demonstrated with high sensitivity and selectivity toward Fe2+ cations. This system is an inorganic/organic hybrid system in which Cu2+ is coordinated at the receptor site of a conjugated polymer sensor. The unique quenching behavior of the Cu2+ toward this conjugated polymer was used to lower the initial fluorescence intensity of the sensory system. This results in a highly sensitive and also selective sensory system toward Fe2+ as compared to other related divalent transition-metal cations in solution. Copyright © 2006 American Chemical Society."

引用

页码：6784 / 6785

页数：2

共 27 条

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[2]

Berne R.M., 1988, PHYSIOLOGY, V3rd, P705

[3]

BERNHARDT PV, 1999, CHEM SOC DA, V20, P3579

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