Dibenzothiophene-bis(oxazolines): new sulfur-containing ligands tested in asymmetric palladium-catalyzed allylic substitutions

被引：24

作者：

Voituriez, A ^{[1
]}

Fiaud, JC ^{[1
]}

Schulz, E ^{[1
]}

机构：

[1] Univ Paris 11, Lab Catalyse Mol, Inst Chim Mol Orsay, UPRESA CNRS 8075, F-91405 Orsay, France

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 28期

关键词：

asymmetric catalysis; dibenzothiophene; bis(oxazolines); palladium; allylic substitutions;

D O I：

10.1016/S0040-4039(02)00962-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New asymmetric sulfur-containing ligands based on a dibenzothiophene backbone have been prepared. The chirality was introduced by two oxazoline moieties placed near the sulfur atom. These C-2-symmetric bis(oxazolines) have been successfully tested in asymmetric palladium-catalyzed allylic substitutions leading to up to 77%, e.e. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：4907 / 4909

页数：3

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