Role of structural factors in the nonlinear optical properties of phthalocyanines and related compounds

被引:1107
作者
de la Torre, G
Váquez, P
Agulló-López, F
Torres, T [1 ]
机构
[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ, Madrid 28049, Spain
[2] Univ Autonoma Madrid, Fac Ciencias, Dept Fis Mat, Madrid 28049, Spain
关键词
D O I
10.1021/cr030206t
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nonlinear optics (NLO) have been drawing interest for a few decades because of their importance in the domains of photoelectronics and photonics. This review covers the important advances obtained to date in the field of the NLO properties phthalocyanines and analogues. Whereas for 1D systems such as polyenes the correlation between structure and NLO response is relatively well developed, much progress is recently being achieved for 2D systems such as Pcs and porphyrins. Such questions as the role of molecular symmetry and multipolar character, metal complexation, peripheral and axial substitution, and core modification are clarified..
引用
收藏
页码:3723 / 3750
页数:28
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