Stable (Amino)(phosphino)carbenes: Difunctional Molecules

被引：82

作者：

Merceon, N

Miqueu, K

Baceiredo, A

Bertrand, G

机构：

[1] Univ Toulouse 3, Lab Heterochim Fondamentale & Appl, UMR 5069, F-31062 Toulouse 04, France

[2] Univ Calif Riverside, Dept Chem, UCR CNRS Joint Res Chem Lab, UMR 2282, Riverside, CA 92521 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 24期

关键词：

D O I：

10.1021/ja026556z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Amino)(phosphino)carbenes are stable due to the donation of the nitrogen lone pair, the phosphino group remains strongly pyramidalized. Reactions can be performed selectively at the carbene center, but also at the phosphorus center leading to new stable carbenes. These difunctional molecules can be considered as hybrid ligands. Copyright © 2002 American Chemical Society.

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页码：6806 / 6807

页数：2

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