Addition of aryl substituents to cyclohexadienyliron electrophiles in the development of routes to C12 central building blocks for alkaloid synthesis

被引：11

作者：

Malkov, AV

Auffrant, A

Renard, C

Rose, E

Rose-Munch, F

Owen, DA

Sandoe, EJ

Stephenson, GR ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci, Norwich NR4 7TJ, Norfolk, England

[2] Univ Paris 06, Lab Synth Organ & Organomet, CNRS, UMR 7611, F-75252 Paris 05, France

来源：

INORGANICA CHIMICA ACTA | 1999年 / 296卷 / 01期

关键词：

acyliron complexes; aryllithium nucleophiles; (aryllithium)chromium complexes; cyclohexadienyliron electrophiles; alkaloid synthesis;

D O I：

10.1016/S0020-1693(99)00390-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel iron-aroyl complexes or synthetically prized arylcyclohexadienyl complexes can be formed from tricarbonyl(eta(5)-1,4-dimethoxycyclohexadienyl)iron(1 +) hexafluorophosphate(1 -) by correct control of reaction sequences that exploit the addition of aryllithium reagents to introduce the aromatic group. Bimetallic products are obtained when a tricarbonylchromium-bound aryllithium reagent or the corresponding cuprate are employed. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：139 / 149

页数：11

共 27 条

[1] USE OF THE ELECTROPHILIC ARYLATION REACTION OF ARYL-LEAD TRIACETATES IN A SYNTHESIS OF (+/-)-LYCORAMINE [J].