F-bonded (1-fluorohexane)pentacarbonyltungsten(0)

被引：5

作者：

Dobson, GR

Smit, JP

Ladogana, S

Walton, WB

机构：

[1] Department of Chemistry, University of North Texas, Denton

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 13期

关键词：

D O I：

10.1021/om970029k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fluoroalkanes, potentially ambidentate, can interact with W through coordination of F or agostically through a three-center, two-electron C(H)-M bond. The site of bonding of 1-fluorohexane to CW(CO)BI in (1-C6H13F)W(CO)(5) generated by pulsed laser flash photolysis of W(CO)(6)/1-fluorohexane solutions in the absence and presence of l-hexene as a trapping nucleophile has been evaluated. The data indicate that W-F bonding is favored and suggest that linkage isomerization takes place through an intramolecular pathway.

引用

页码：2858 / 2861

页数：4

共 24 条

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