Surface structure of MBE-grown Fe3O4(001) by X-ray photoelectron diffraction and scanning tunneling microscopy

被引:90
作者
Chambers, SA [1 ]
Thevuthasan, S [1 ]
Joyce, SA [1 ]
机构
[1] Pacific NW Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA
关键词
iron oxide; low index single crystal surfaces; photoelectron diffraction; scanning tunneling microscopy; surface relaxation and reconstruction; surface structure; morphology; roughness; and topography;
D O I
10.1016/S0039-6028(00)00230-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have investigated the surface termination and interlayer relaxations of (root 2 x root 2)R45 degrees-Fe3O4(001) as grown on MgO(001) by oxygen-plasma-assisted molecular beam epitaxy. Despite the fact that autocompensated surfaces can be constructed in principle by terminating with either a half layer of tetrahedral Fe, or a modified layer of octahedral Fe plus tetrahedral O, the combination of photoelectron diffraction and scanning tunneling microscopy suggests the former. The first four interlayer spacings are relaxed by -14, -57, -19, and +29% of the respective bulk value. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:L273 / L279
页数:7
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