In-situ end-group functionalization of regioregular poly(3-alkylthiophene) using the Grignard metathesis polymerization method

被引:231
作者
Jeffries-El, M [1 ]
Sauvé, G [1 ]
McCullough, RD [1 ]
机构
[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
关键词
D O I
10.1002/adma.200400137
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile one-step synthetic method to functionalize regioregular polythiophene is described (see Figure). End-group functionalization leads to a number of new uses for these polymers including end-group-driven self-assembly onto surfaces and into conducting polymer networks, and their use as building blocks for the synthesis of block copolymers. [GRAPHICS]
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页码:1017 / +
页数:4
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