Low temperature activation of benzylic C-H bonds with heterogeneous Fe/MgO catalyst under atmospheric molecular oxygen

被引：20

作者：

Cho, SH

Cheong, MS

Jung, KD

Kim, CS

Han, SH

机构：

[1] Hanyang Univ, Dept Chem, Sungdong Ku, Seoul 133791, South Korea

[2] Kookmin Univ, Dept Phys, Sungdong Ku, Seoul 133791, South Korea

[3] Kyung Hee Univ, Dept Chem, Sungdong Ku, Seoul 133791, South Korea

[4] Korea Inst Sci & Technol, Eco Nano Res Ctr, Sungdong Ku, Seoul 133791, South Korea

来源：

APPLIED CATALYSIS A-GENERAL | 2004年 / 267卷 / 1-2期

关键词：

C-H activation; oxidation; catalysis; Fe/MgO;

D O I：

10.1016/j.apcata.2004.03.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The room temperature benzylic oxidation was per-formed with Fe/MgO catalyst. This Fe/MgO catalyst was prepared by the dissolution-precipitation method. This heterogeneous catalyst, Fe/MgO, activated the C-H bond with atmospheric molecular oxygen even at 10degreesC; its catalytic activity was greatly enhanced by the addition of N-hydroxyphthalimide (NHPI) and/or acetaldehyde. (C) 2004 Elsevier B.V. All rights reserved.

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收藏

页码：241 / 244

页数：4

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