Neutron diffraction investigations of the cation coordination in an amorphous polymer electrolyte, PPO-LiClO4

被引：8

作者：

Carlsson, P ^{[1
]}

Swenson, J

Börjesson, L

McGreevy, RL

Jacobsson, P

Torell, LM

Howells, WS

机构：

[1] Chalmers Univ Technol, Dept Phys, S-41296 Gothenburg, Sweden

[2] Chalmers Univ Technol, Dept Appl Phys, S-41296 Gothenburg, Sweden

[3] Studsv Neutron Res Lab, S-61182 Nykoping, Sweden

[4] Rutherford Appleton Lab, Didcot OX11 0QX, Oxon, England

来源：

ELECTROCHIMICA ACTA | 2000年 / 45卷 / 8-9期

关键词：

amorphous polymer electrolyte; neutron diffraction; cation coordination;

D O I：

10.1016/S0013-4686(99)00358-8

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The structure of an amorphous polymer electrolyte model material, PPO-LiClO4, has been investigated on the short-range length scale using neutron diffraction H/D isotope substitution experiments. We report experimental results which may be attributed to a lithium ether-oxygen distance of about 2.1 Angstrom The findings indicate, within the experimental accuracy, that the cation environment of the Li+ ion in PPO-LiClO4 O:M = 16:1 is approximately the same as reported for crystalline and amorphous complexes of PEO and lithium salts. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1449 / 1452

页数：4

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