X-ray crystallographic study on single-crystalline photochromism of bis(2,5-dimethyl-3-thienyl)perfluorocyclopentene

被引：154

作者：

Yamada, T

Kobatake, S

Muto, K

Irie, M

机构：

[1] Kyushu Univ, Dept Chem & Biochem, Grad Sch Engn, Higashi Ku, Fukuoka 8128581, Japan

[2] Japan Sci & Technol Corp, CREST, Higashi Ku, Fukuoka 8128581, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2000年 / 122卷 / 08期

关键词：

D O I：

10.1021/ja993289x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The single-crystalline cycloreversion reaction of a photochromic diarylethene, bis(2,5-dimethyl-3-thienyl)perfluorocyclopentene, was studied by X-ray single-crystal structure analysis. The single crystal of the closed-ring form isomer was irradiated with 680 nm light and formation of the open-ring form isomer was followed. The crystal structure analysis revealed that the cycloreversion reaction proceeded in the single crystal in a conrotatory mode.

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页码：1589 / 1592

页数：4

相关论文

共 18 条

[1] PHOTOCHROMISM DEPENDENT ON CRYSTAL PACKING - PHOTOINDUCED AND THERMAL PROTON-TRANSFER PROCESSES IN SINGLE-CRYSTALS OF 6-(2,4-DINITROBENZYL)-2,2'-BIPYRIDINE [J].

EICHEN, Y ;

LEHN, JM ;

SCHERL, M ;

HAARER, D ;

FISCHER, J ;

DECIAN, A ;

CORVAL, A ;

TROMMSDORFF, HP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (22) :2530-2533

[2] PHOTOCHROMISM AND THERMOCHROMISM OF SCHIFF-BASES IN THE SOLID-STATE AND IN RIGID GLASSES [J].

HADJOUDIS, E ;

VITTORAKIS, M ;

MOUSTAKALIMAVRIDIS, I .

TETRAHEDRON, 1987, 43 (07) :1345-1360

[3] X-ray analysis of structural changes in photochromic salicylideneaniline crystals. Solid-state reaction induced by two-photon excitation [J].

Harada, J ;

Uekusa, H ;

Ohashi, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (24) :5809-5810

[4] PHOTOCHROMISM OF SINGLE-CRYSTALLINE DIARYLETHENES [J].

IRIE, M ;

UCHIDA, K ;

ERIGUCHI, T ;

TSUZUKI, H .

CHEMISTRY LETTERS, 1995, (10) :899-900

[5] PHOTOCHROMIC DIARYLETHENES WITH INTRALOCKING ARMS [J].

IRIE, M ;

MIYATAKE, O ;

UCHIDA, K ;

ERIGUCHI, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (22) :9894-9900

[6] Synthesis and properties of photochromic diarylethenes with heterocyclic aryl groups [J].

Irie, M ;

Uchida, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (05) :985-996

[7] PHOTOCHROMIC AND THERMOCHROMIC COMPOUNDS .1. STRUCTURES OF (E) AND (Z) ISOMERS OF 2-ISOPROPYLIDENE-3-[1-(2-METHYL-5-PHENYL-3-THIENYL)ETHYLIDENE]SUCCINICANHYDRIDE, C20H18O3S, AND THE PHOTOPRODUCT 7,7A-DIHYDRO-4,7,7,7A-TETRAMETHYL-2-PHENYLBENZO[B]THIOPHENE-5,6-DICARBOXYLIC ANHYDRIDE (P), C20H18O3S [J].

KAFTORY, M .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (JUN) :1015-1019

[8] The first in situ direct observation of the light-induced radical pair from a hexaarylbiimidazolyl derivative by X-ray crystallography [J].

Kawano, M ;

Sano, T ;

Abe, J ;

Ohashi, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (35) :8106-8107

[9] Photochromism of 1,2-bis(2,5-dimethyl-3-thienyl)perfluorocyclopentene in a single crystalline phase [J].

Kobatake, S ;

Yamada, T ;

Uchida, K ;

Kato, N ;

Irie, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (11) :2380-2386

[10] Photochromism of 1,2-bis(2-methyl-6-nitro-1-benzothiophen-3-yl) perfluorocyclopentene in a single-crystalline phase: Dichroism of the closed-ring form isomer [J].

Kobatake, S ;

Yamada, M ;

Yamada, T ;

Irie, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (37) :8450-8456