Re-entrant glass transition in a colloid-polymer mixture with depletion attractions

被引:307
作者
Eckert, T [1 ]
Bartsch, E [1 ]
机构
[1] Johannes Gutenberg Univ Mainz, Inst Phys Chem, D-55099 Mainz, Germany
关键词
D O I
10.1103/PhysRevLett.89.125701
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Performing light scattering experiments we show that introducing short-ranged attraction to a colloid suspension of nearly hard spheres by addition of a free polymer produces new glass-transition phenomena. We observe a dramatic acceleration of the density fluctuations amounting to the melting of a colloidal glass. Upon increasing the strength of the attractions the system freezes into another nonergodic state sharing some qualitative features with gel states occurring at lower colloid packing fractions. This re-entrant glass transition is in qualitative agreement with recent theoretical predictions.
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页数:4
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