Molecular peapods as supramolecular carbon allotropes

被引:69
作者
Vostrowsky, O [1 ]
Hirsch, A [1 ]
机构
[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany
关键词
fullerenes; metallocenes; molecular peapods; nanotubes; porphyrins;
D O I
10.1002/anie.200301749
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A high-tech alternative to diamond and graphite: Supramolecular carbon allotropes are formed when single-walled carbon nanotubes are filled with C 60 molecules. Similar molecular peapods"are also obtained by insertion of endohedral fullerenes and metallocenes into carbon nanotubes. Supramolecular nanotubes built up from porphyrins can also encapsulate C 60 peas."
引用
收藏
页码:2326 / 2329
页数:4
相关论文
共 48 条
[1]   Structural transformation from single-wall to double-wall carbon nanotube bundles [J].
Abe, M ;
Kataura, H ;
Kira, H ;
Kodama, T ;
Suzuki, S ;
Achiba, Y ;
Kato, K ;
Takata, M ;
Fujiwara, A ;
Matsuda, K ;
Maniwa, Y .
PHYSICAL REVIEW B, 2003, 68 (04)
[2]   Nanotubes from carbon [J].
Ajayan, PM .
CHEMICAL REVIEWS, 1999, 99 (07) :1787-1799
[3]   Covalent chemistry of single-wall carbon nanotubes [J].
Bahr, JL ;
Tour, JM .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) :1952-1958
[4]   Raman scattering study of double-wall carbon nanotubes derived from the chains of fullerenes in single-wall carbon nanotubes [J].
Bandow, S ;
Takizawa, M ;
Hirahara, K ;
Yudasaka, M ;
Iijima, S .
CHEMICAL PHYSICS LETTERS, 2001, 337 (1-3) :48-54
[5]   Selective host-guest interaction of single-walled carbon nanotubes with functionalised fullerenes [J].
Britz, DA ;
Khlobystov, AN ;
Wang, JW ;
O'Neil, AS ;
Poliakoff, M ;
Ardavan, A ;
Briggs, GAD .
CHEMICAL COMMUNICATIONS, 2004, (02) :176-177
[6]   Temperature dependence of conductance character in nanotube peapods [J].
Chiu, PW ;
Yang, SF ;
Yang, SH ;
Gu, G ;
Roth, S .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2003, 76 (04) :463-467
[7]   Temperature-induced change from p to n conduction in metallofullerene nanotube peapods [J].
Chiu, PW ;
Gu, G ;
Kim, GT ;
Philipp, G ;
Roth, S ;
Yang, SF ;
Yang, S .
APPLIED PHYSICS LETTERS, 2001, 79 (23) :3845-3847
[8]  
Dai LM, 2001, ADV MATER, V13, P899, DOI 10.1002/1521-4095(200107)13:12/13<899::AID-ADMA899>3.0.CO
[9]  
2-G
[10]   Specific Raman signatures of a dimetallofullerene peapod -: art. no. 085501 [J].
Débarre, A ;
Jaffiol, R ;
Julien, C ;
Nutarelli, D ;
Richard, A ;
Tchénio, P .
PHYSICAL REVIEW LETTERS, 2003, 91 (08)