Kinetic control of stereoselectivity of halide substitution in arene ruthenium pyridyloxazoline complexes; a rare case of net inversion

被引：15

作者：

Davenport, AJ ^{[1
]}

Davies, DL ^{[1
]}

Fawcett, J ^{[1
]}

Garratt, SA ^{[1
]}

Russell, DR ^{[1
]}

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 23期

关键词：

D O I：

10.1039/a907873h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [RuCl(Pr-i-pymox)(eta(6)-mes)](+) 1b [Pr-i-pymox = 4-isopropyl-2-(2-pyridyl)-1,3-oxazoline, mes = 1,3,5-trimethylbenzene] with AgSbF6 then with halide gives [RuX(Pr-i-pymox)(eta(6)-mes)](+) (X = Cl 1, Br 2, I 3), each as a mixture of diastereomers, the kinetic product being formed preferentially with net inversion of configuration at the metal; the structures of 2a and 2b have been determined by X-ray crystallography.

引用

页码：2331 / 2332

页数：2

共 15 条

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