Physical characterization of B1 and B2 phases in a newly synthesized series of banana shaped molecules

被引:58
作者
Bedel, JP
Rouillon, JC
Marcerou, JP
Laguerre, M
Achard, MF
Nguyen, HT
机构
[1] Univ Bordeaux 1, Ctr Rech Paul Pascal, F-33600 Pessac, France
[2] Univ Bordeaux 1, Ecole Polytech, Inst European Chim & Biol, F-33402 Talence, France
关键词
D O I
10.1080/026782900203272
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new homologous series of achiral banana-shaped mesogens ('Cn') has been synthesized and studied by classical techniques (optical microscopy, differential scanning calorimetry, X-ray diffraction and electro-optic investigations). Complete miscibility with compounds of the n-OPIMB series shows that the short homologues (C5-C9) exhibit a frustrated B1 antiphase, while the longer members (C10-C14) present a B2 smectic C phase. Electro-optic measurements confirm this identification.
引用
收藏
页码:103 / 113
页数:11
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