Use of waste fats of animal and vegetable origin for the production of biodiesel fuel: Quality, motor properties, and emissions of harmful components

被引:58
作者
Lebedevas, Sergejus
Vaicekauskas, Andrius
Lebedeva, Galina
Makareviciene, Violeta [1 ]
Janulis, Prutenis
Kazancev, Kiril
机构
[1] Lithuanian Univ Agr, Lab Chem & Biochem Res Environm Technol, LT-53361 Kaunas, Lithuania
[2] Klaipeda Univ, Fac Nat Sci & Math, Dept Comp Sci, LT-92294 Klaipeda, Lithuania
[3] Klaipeda Univ, Maritime Inst, Dept Marine Engn, LT-92123 Klaipeda, Lithuania
关键词
D O I
10.1021/ef060145c
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
One of the ways to reduce the price of biodiesel fuel is to use waste fats of animal and vegetable origin. The objective of this work was to investigate the physical and chemical properties of the fatty acid methyl esters of animal and vegetable origin and their mixtures, to determine their motor characteristics, to choose the optimal composition of biofuel mixtures, and to perform comparative analyses of emissions of harmful components in exhaust gases. It was determined that pure fatty acid methyl esters of animal origin and linseed oil fatty acid methyl esters do not meet standard requirements and cannot be used directly in diesel engines. For diesel engines, three-component mixtures of rapeseed oil methyl esters (RME), pork lard methyl esters (PME) or beef tallow methyl esters (TME), and linseed oil methyl esters (LME) (where the proportion of LME and methyl esters of animal origin is 1:4) may be used as fuel. According to the comparative analyses of motor characteristics of three-component mixtures, they are practically equal to the certified RME and its mixtures with fossil diesel fuel. If these three-component mixtures are used for the high-speed diesel engine, CO emissions are reduced by 20%-50%, hydrocarbon (HC) emissions are reduced by 50%-60%, and the smoke opacity of the exhaust gases is reduced by 25%-70%. The increase in NOx emissions does not exceed 13%; no significant changes in the CO2 emissions have been noticed. When the mixtures with fossil diesel fuel that contained 30% of the aforementioned three-component biofuel mixtures were tested, CO emissions were reduced by 15%-40%, HC emissions were reduced by 30%-45%, and the smoke opacity was reduced by 25%-30%. The NOx emissions increased similar to 6%; there were no notable changes in CO2 emissions.
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页码:2274 / 2280
页数:7
相关论文
共 19 条
[1]  
*BIOB PROJ COMM, BIO BUS FIN REP BIOD
[2]  
CHOI CY, 1997, MECHANISMS EMISSIONS
[3]   Optimization of enzymatic production of biodiesel from castor oil in organic solvent medium [J].
Débora de Oliveira ;
Marco Di Luccio ;
Carina Faccio ;
Clarissa Dalla Rosa ;
João Paulo Bender ;
Nádia Lipke ;
Silvana Menoncin ;
Cristiana Amroginski ;
José Vladimir de Oliveira .
Applied Biochemistry and Biotechnology, 2004, 115 (1-3) :771-780
[4]   LOW-TEMPERATURE PROPERTIES OF TRIGLYCERIDE-BASED DIESEL FUELS - TRANSESTERIFIED METHYL-ESTERS AND PETROLEUM MIDDLE DISTILLATE/ESTER BLENDS [J].
DUNN, RO ;
BAGBY, MO .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1995, 72 (08) :895-904
[5]   Low-temperature properties of alkyl esters of tallow and grease [J].
Foglia, TA ;
Nelson, LA ;
Dunn, RO ;
Marmer, WN .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1997, 74 (08) :951-955
[6]   Jatropha curcas L as a source for the production of biofuel in Nicaragua [J].
Foidl, N ;
Foidl, G ;
Sanchez, M ;
Mittelbach, M ;
Hackel, S .
BIORESOURCE TECHNOLOGY, 1996, 58 (01) :77-82
[7]   Engine performance of biodiesel fuel prepared from soybean soapstock: A high quality renewable fuel produced from a waste feedstock [J].
Haas, MJ ;
Scott, KM ;
Alleman, TL ;
McCormick, RL .
ENERGY & FUELS, 2001, 15 (05) :1207-1212
[8]   Production of alkyl esters from tallow and grease using lipase immobilized in a phyllosilicate sol-gel [J].
Hsu, AF ;
Jones, K ;
Marmer, WN ;
Foglia, TA .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2001, 78 (06) :585-588
[9]  
KORBITZ W, 1998, REV COMMERICAL PRODU, P3
[10]   USE OF BRANCHED-CHAIN ESTERS TO REDUCE THE CRYSTALLIZATION TEMPERATURE OF BIODIESEL [J].
LEE, I ;
JOHNSON, LA ;
HAMMOND, EG .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1995, 72 (10) :1155-1160