High-concentration dispersion of single-wall carbon nanotubes

被引:153
作者
Sabba, Y [1 ]
Thomas, EL [1 ]
机构
[1] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA
关键词
D O I
10.1021/ma049706u
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We report a novel method to exfoliate and disperse single-wall carbon nanotubes (SWNT) into organic and aqueous solutions. The method is based on treatment of single-wall carbon nanotubes with a solution of hydroxylamine hydrochloric acid salt [(NH2OH)(HCl)] and does not require truncation of the tubes or surface adsorption of organic molecules. The solution dispersed tubes can easily be incorporated into an organic matrix in order to obtain a nanocomposite. We illustrate the method by forming PMMA-SWNT and PS-SWNT nanocomposites. 1% SWNT PMMA nanocomposite having a draw ratio of similar to6 showed a dramatic 7x increase in the strain to fracture compared to fibers of similar draw ratio made from pure PMMA.
引用
收藏
页码:4815 / 4820
页数:6
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