Synthesis of a beta-turn forming depsipeptide for hydrogen bond mediated electron transfer studies

被引：16

作者：

Williamson, DA ^{[1
]}

Bowler, BE ^{[1
]}

机构：

[1] UNIV DENVER,DEPT CHEM & BIOCHEM,DENVER,CO 80208

来源：

TETRAHEDRON | 1996年 / 52卷 / 38期

关键词：

D O I：

10.1016/0040-4020(96)00743-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrogen bonds ate believed to play an important role in the mediation of electron transfer processes in proteins. A porphyrin/depsipeptide/p-benzoquinone molecule has been synthesized to help understand this role of hydrogen bond mediated electron transfer in proteins. The synthesis, room temperature folding conformation. and steady-state electron transfer are described. Copyright (C) 1996 Elsevier Science Ltd

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页码：12357 / 12372

页数：16

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