Intercalation of organic molecules into vanadium(IV) benzenedicarboxylate: Adsorbate structure and selective absorption of organosulfur compounds

被引：110

作者：

Wang, Xiqu ^{[1
]}

Liu, Lumei ^{[1
]}

Jacobson, Allan J. ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 39期

关键词：

host-guest systems; intercalation; metal-organic frameworks; selective absorption; vanadium;

D O I：

10.1002/anie.200602556

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A very good host: The guest acid molecules of hydrothermally synthesized [V(O)(bdc)](H2bdc)0.71 (bdc = benzenedicarboxylate) are removed to give high-quality single crystals of [V(O)(bdc)] (1). On absorption of guest molecules from the liquid phase, 1 undergoes crystal-to-crystal transformations (aniline: 2; thiophene: 3; acetone: 4). Furthermore, complex 1 also selectively absorbs thiophene and dimethyl sulfide from methane. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6499 / 6503

页数：5

共 45 条

[1] Zinc saccharate: A robust, 3D coordination network with two types of isolated, parallel channels, one hydrophilic and the other hydrophobic [J].