Spinnability of polymer melts - A complex problem in basic research

被引:25
作者
Beyreuther, R
Vogel, R
机构
[1] Institute of Polymer Research, Dresden
[2] Inst. of Polymer Research Dresden, 01005, 01069 Dresden
关键词
D O I
10.3139/217.960154
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Melt spinning of polymer melts is a formation process making extremely high demands on the material's continuous deformation ability by highest deformation speeds. The structural conditions of a thermoplastic polymer which are necessary for spinnability have not been exactly cleared up yet. But this knowledge gap must be closed especially with regard to the many efforts to spin fibers with new properties made from modified polymers of polymer blends. The article is begun with a pragmatic definition of the spinnability of a polymer melt. The discussion of a structural rheological model shows a correlation between dynamic rheological measurement datas of polymer melts and experimental experience about their spinnability. Proceeding from a comprehensive description of possible failure cases (fiber beak problems), results of rheological measurement of a number of different polymers, which are spinnable well, not as well or not at all, are compared. The article is concluded by some comments on open problems which have to be solved by basic research in the near future.
引用
收藏
页码:154 / 158
页数:5
相关论文
共 8 条
[1]   EFFECTS OF PROCESSING PARAMETERS AND MOLECULAR-WEIGHT DISTRIBUTION ON THE TENSILE PROPERTIES OF POLYPROPYLENE FIBERS [J].
ANDREASSEN, E ;
MYHRE, OJ ;
HINRICHSEN, EL ;
GROSTAD, K .
JOURNAL OF APPLIED POLYMER SCIENCE, 1994, 52 (10) :1505-1517
[2]  
Dealy J.M., 1990, MELT RHEOLOGY ITS RO
[3]   FREQUENCY-RESPONSE ANALYSIS OF POLYMER MELT-SPINNING [J].
DEVEREUX, BM ;
DENN, MM .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (10) :2384-2390
[4]   MELT STRENGTH BEHAVIOR OF POLYPROPYLENES [J].
GHIJSELS, A ;
DECLIPPELEIR, J .
INTERNATIONAL POLYMER PROCESSING, 1994, 9 (03) :252-257
[5]   A COLLABORATIVE STUDY OF THE STABILITY OF EXTRUSION, MELT SPINNING AND TUBULAR FILM EXTRUSION OF SOME HIGHLOW, LOWLOW AND LINEAR-LOW DENSITY POLYETHYLENE SAMPLES [J].
WHITE, JL ;
YAMANE, H .
PURE AND APPLIED CHEMISTRY, 1987, 59 (02) :193-216
[6]   A COLLABORATIVE STUDY OF THE RHEOLOGICAL PROPERTIES AND UNSTABLE MELT SPINNING CHARACTERISTICS OF LINEAR AND BRANCHED POLYETHYLENE TEREPHTHALATES [J].
WHITE, JL ;
YAMANE, H .
PURE AND APPLIED CHEMISTRY, 1985, 57 (10) :1441-1452
[8]   NECKING IN HIGH-SPEED SPINNING REVISITED [J].
ZIABICKI, A ;
TIAN, JJ .
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS, 1993, 47 :57-75