Trigold triacetylides: Polymerization through gold center dot center dot center dot gold bonding or bridging ligands

被引：59

作者：

Irwin, MJ

ManojlovicMuir, L

Muir, KW

Puddephatt, RJ

Yufit, DS

机构：

[1] UNIV GLASGOW, DEPT CHEM, GLASGOW G12 8QQ, LANARK, SCOTLAND

[2] UNIV WESTERN ONTARIO, DEPT CHEM, LONDON, ON N6A 5B7, CANADA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 02期

关键词：

D O I：

10.1039/a607214c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new trigold(I) triacetylide [C6H3(C=CAu)(3)-1,3,5] reacts with monodentate ligands, L = isocyanide, phosphite or phosphine, to give [C6H3(C=C AuL)(3)-1,3,5] complexes which form polymeric solids with intermolecular Au Au bonding; it also reacts with bidentate ligands to give covalently linked network polymers of the formula [{C6H3(C=C AU)(3)-1,3,5}(2)(mu-L-L)(3)], L-L = diisocyanide or diphosphine.

引用

页码：219 / 220

页数：2

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