Step-gradient capillary electrochromatography

被引：36

作者：

Euerby, MR ^{[1
]}

Gilligan, D ^{[1
]}

Johnson, CM ^{[1
]}

Bartle, KD ^{[1
]}

机构：

[1] UNIV LEEDS,SCH CHEM,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND

来源：

ANALYST | 1997年 / 122卷 / 10期

关键词：

step-gradient; capillary electrochromatography; diuretic analysis; repeatability;

D O I：

10.1039/a703175k

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The analytical benefits of using a step-gradient in; capillary electrochromatography (CEC) are demonstrated. The application of step-gradient CEC to the analysis of six diuretics of widely differing lipophilicities was evaluated and shown to result in a marked reduction in the analysis time and an improvement in the peak shape for later-eluting lipophilic components. When the step-gradient approach was performed in an automated mode, the retention time RSD for repeated injections was below 1%.

引用

页码：1087 / 1088

页数：2

共 8 条

[1] GRADIENT ELUTION SYSTEM FOR PACKED CAPILLARY COLUMN LIQUID-CHROMATOGRAPHY [J].