Characterization of intraligand charge transfer transitions in Pd(qol)(2), Pt(qol)(2) and Pt(qtl)(2) investigated by Shpol'skii spectroscopy

被引：26

作者：

Donges, D

Nagle, JK

Yersin, H

机构：

[1] UNIV REGENSBURG,INST PHYS & THEORET CHEM,D-93040 REGENSBURG,GERMANY

[2] BOWDOIN COLL,DEPT CHEM,BRUNSWICK,ME 04011

来源：

JOURNAL OF LUMINESCENCE | 1997年 / 72-4卷

关键词：

Shpol'skii spectroscopy; intraligand charge transfer; platinum metal compounds; spin polarization;

D O I：

10.1016/S0022-2313(96)00207-4

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Pd(qol)(2), Pt(qol)(2) and Pt(qtl)(2) are investigated in n-octane Shpol'skii matrices at T = 1.2 K. For the first time, it is possible to obtain highly resolved phosphorescence and triplet as well as singlet excitation spectra. The corresponding excited states are assigned to intraligand charge transfer (ILCT) transitions. Their characteristic electronic and vibrational properties are studied in detail.

引用

页码：658 / 659

页数：2

共 7 条

[1] PHOSPHORESCENT 8-QUINOLINOL METAL-CHELATES - EXCITED-STATE PROPERTIES AND REDOX BEHAVIOR [J].