A convenient, transition metal-catalyzed route to water-soluble amphiphilic organometallic block copolymers:: Synthesis and aqueous self-assembly of poly(ethylene oxide)-block-poly(ferrocenylsilane)

被引：52

作者：

Resendes, R ^{[1
]}

Massey, J ^{[1
]}

Dorn, H ^{[1
]}

Winnik, MA ^{[1
]}

Manners, I ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

MACROMOLECULES | 2000年 / 33卷 / 01期

关键词：

D O I：

10.1021/ma991450i

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis and aqueous assembly of a poly(ethylene oxide)(PEO)-block-poly(ferrocenylsilane)(PFS) block copolymer is described. The transition metal-catalyzed anionic ring-opening polymerization of dimethylsila ferrocenophane in the presence of Si-H end-functionalized polyethylene glycol methyl ether affords a PEO-b-PFS amphiphilic block copolymer which self-assembles into spherical micelles in aqueous solution. This method represents a facile and convenient route toward incorporating PEO into an organometallic block copolymer architecture. Furthermore, this represents an example of an amphiphilic, water-soluble organometallic block copolymer.

引用

页码：8 / 10

页数：3

共 24 条

[1] Preparation of mesoporous silica with poly(oxyethylene)/poly(oxybutylene)/poly(oxyethylene) triblock copolymers as templates [J].