Aromatic donor-acceptor charge-transfer and metal-ion-complexation-assisted folding of a synthetic polymer

被引：124

作者：

Ghosh, S ^{[1
]}

Ramakrishnan, S ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 25期

关键词：

charge transfer; donor-acceptor systems; polymers; solvophobic effect; supramolecular chemistry;

D O I：

10.1002/anie.200453860

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Designer folds: The interplay of three design elements (aromatic donor-acceptor charge-transfer complexation, solvophobic effect, and metal-ion complexation) guided the preparation of a folded structure (see picture) in a synthetic macromolecule. Evidence for this is provided by UV/Vis and 1H NMR spectroscopy.

引用

页码：3264 / 3268

页数：5

共 36 条

[1]

Ajayaghosh A, 2002, ANGEW CHEM INT EDIT, V41, P1766, DOI 10.1002/1521-3773(20020517)41:10<1766::AID-ANIE1766>3.0.CO

[2]

2-4

[3]

Ajayaghosh A., 2002, ANGEW CHEM, V114, P1844

[4]

[Anonymous], 1969, ORGANIC CHARGE TRANS