Synthesis of a boron-containing conducting polymer from the anodic oxidation of Tris(pyrrolyl)borane

被引：10

作者：

Douglade, G ^{[1
]}

Fabre, B ^{[1
]}

机构：

[1] Univ Rennes 1, Unite Mixte Rech 6510 CNRS, Lab Electrochim Mol & Macromol, F-34042 Rennes, France

来源：

SYNTHETIC METALS | 2002年 / 129卷 / 03期

关键词：

pyrrole; boron; conducting polymers;

D O I：

10.1016/S0379-6779(02)00055-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrochemical oxidation of Tris(N pyrrolyl)borane (1) in THF yielded a conducting polymer film with an electron conductivity of ca 7 x 10(-4) S cm(-1) The coulometric measurements indicated that the three pyrrolyl units were not totally coupled during the electropolymerization reaction From further UV-VIS and FTIR spectroscopy data a structure of poly(1) was then proposed (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：309 / 314

页数：6

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